Keywords chemical bath deposition, cadmium sulphide, band gap energy. Jeya rajendran advanced materials research laboratory, department of chemistry, loyola college, chennai, tn, india. P under my guidance, at the department of physics, cochin university of science and technology, and has not been included in any other thesis submitted previously for the award of any degree. Cadmium sulfide definition is a yellowbrown poisonous salt cds used especially in electronic parts, in photoelectric cells, and in medicine. Jack lewis research center summary unprotected and protected np silicon and encapsulated cadmium sulfide solar cells were exposed to a simulated micrometeoroid environment.
The cadmium sulfide nanoparticles have been prepared by chemical co. Graph to find the band gap of cadmium sulfide nanoparticles. Cadmium sulfide definition of cadmium sulfide by merriam. Low temperature photoluminescence studies on sputter deposited cadmium sulphidecadmium telluride heterojunctions and solar cells by mohit tuteja thesis submitted in partial fulfillment of the requirements for the degree of master of science in materials science and engineering in the graduate college of the.
Czt is deposited by cosublimation of cdte and znte. The invention relates to the manufacture of cadmium sulphide solar cells. Thin films of cadmium sulphide with thicknesses ranging from 0. Planar heterojunction perovskite solar cell is one of the most competitive photovoltaic technologies, while charge transport materials play a crucial role. Cadmium sulphide incorporated reduced graphene oxide as counter electrode for dye sensitized solar cell free download abstract. The cadmium sulfide photovoltaic cell,12 which was discovered there in 1954, paved the way to the development of a practical thin film solar cell. Cadmium sulphide incorporated reduced graphene oxide as counter electrode for dye sensitized solar cell sandhya murali, f. Aterials and ethods commercially available cadmium sulphide cds powder and 10%wt cadmium chloride cdcl. This work involves characterization of cadmium zinc telluride films and solar cells prepared by close spaced sublimation. Cadmium telluride cdte photovoltaics describes a photovoltaic pv technology that is based on the use of cadmium telluride in a thin semiconductor layer designed to absorb and convert sunlight into electricity. Cadmiumsulphidecoppersulphide thinfilm solar cells.
A thin layer of cds of about 200 a enhances the solar conversion efficiency of cdscdte solar cells from 8% to 15%. A cell is formed of a glass substrate 10, a front contact 12 made, for example, of tin oxide, a cadmium sulphide layer 14 and a copper sulphide layer 16. From the graph, the optical band gap of cadmium sulfide nanoparticles is 3ev. The cathodic electrodeposition of cadmium sulphide from a nonaqueous solution bath has been developed. D polytechnic university of turin, italy cadmium sulfide nanopowder cdsn is remarkable electron acceptor for hybrid solar cell applications. A description is also given of some less commonly used methods that might be developed into. There is a great interest to replace the cadmium sulphide cds thin film by a cadmiumfree wide band gap buffer layer in solar cell applications, for environmental reasons and possible gains in efficiency associated with an in crease in the short circuit current. The zns film was also deposited using the same procedure. Applications of graphene or its derivatives in solar cells and reported device performance. Zinc cadmium sulphide and zinc sulphide as alternative. Photovoltaic cells based on copper phthalocyanine and cadmium sulfide heterojunction this work focuses on the solar cell based on the heterostructure formed between copper phthalocyanine cupc and cadmium sulfide cds. The paper also presents some findings on how to optimize the chemical bath deposition. The final solar cell efficiency was 10% indicating goodquality layers and junctions. The spin coated mesoporous tio 2 layers on ito glass substrates were sensitized with cadmium sulphidecadmium selenide quantum dots using different number of silar successive ionic layer adsorption and reaction cycles.
Hybrid photovoltaic pv cells based on cadmium sulphide cds single crystal and phthalocyanine pc films have been developed and their pv performance was measured. The fabrication of merocyanine cadmium sulphide solar. Solar cells cadmium sulfide cadmium sulfide is a semiconductor that has a very wide band gap of about 2. We have successfully fabricated cds homojunction solar cell with a. The cds layer was produced by spray pyrolysis of cadmium chloride and thiourea and the dye then spin coated on top of this cds film. The development of the semicontinuous spray process is outlined. Effect of annealing on the structural and photovoltaic. Application of pn junctions within solar cells is discussed. The photovoltaic effect in cadmium sulfide cds was discovered by reynolds in. Pdf fabrication and characterization of cadmium sulfide cds.
We successfully demonstrated an effective electron transport material, namely chemical bath deposited cadmium sulphide cds film under low temperature, in perovskitebased solar cells. Synthesis and characterization of cadmium sulfide nanoparticles for the applications of dye sensitized solar cell f. Cds thin film solar cells have now been under development for a period of 12 years ref. Pdf investigation of the properties of cadmium sulphide. Tech indian institute of technology madras, 2005 a thesis submitted in partial fulfillment of the requirements for the degree of master of science in the department of mechanical, materials and aerospace engineering.
Cds films have been prepared by electrodeposition using elemental sulphur 9 or. Photoelectrochemical cell a photoelectrochemical solar cell generally considered to exemplify the promise of these devices is that employing cdse as the photoelectrode, in comhination with an alkaline aqueous s,12, sz2 redox electrolyte. Thin film by using chemical bath deposition method for solar cell. A decade later it was observed that a layer of cadmium sulfide on top could increase the conversion efficiency from about 5% to about 8%. It exhibits intrinsic ntype of conductivity caused by sulphur vacancies due to excess cadmium atoms 1.
The promise of clean, cheap, and abundant electricity from the sun has been the dream of many scientists and businesses. Cadmium sulfide solar cell powder high purity less price. The obtained cdsnta showed a random distribution of. Cadmium telluride pv is the only thin film technology with lower costs than conventional solar cells made of crystalline silicon in multikilowatt systems. Cadmium sulfide nanoparticles cdsn are excellent electron acceptor for hybrid solar cell applications. Pdf cadmium sulfide nanoparticles synthesized by microwave. Cadmiumsulphidecoppersulphide thinfilm solar cells ieee xplore. Five different pcs have been selected as candidates for the pv cell, pccu, pcmn, pczn, pcmg, and pcvo. Indium sulphide in xs y is a prominent candidate to be an alternative buffer layer to socalled toxic cadmium sulphide cds in cis based solar cells. We give the upper limit to the solar cell e ciency. Cadmium sulphide cds is a iivi semiconductor which is insoluble in water, but soluble in dilute mineral acids. Highperformance cadmium sulphidebased planar perovskite.
Thinfilm photovoltaic copper indium gallium diselenide solar string or cell trade names. Since the early 1950s, cadmium telluride has been known as a good candidate for solar cells since it could be doped n and ptype and its band gap at 1. Performance of nip silicon and cadmium sulfide solar cells as affected by hypervelocity particle impact by robert l. The paper presents an investigation of the properties of cadmium sulphide cds thin films and their suitability for use as solar cell material. However in the last 20 years other thin films solar cells have taken the place of the cuprous sulfidecadmium sulfide, and their efficiency have raised up to almost. G2 thin film string or generation2 single cell part number. Cadmium sulfide is used as pigment in paints, plastics, textiles, ceramic and glass and is also used in solar cells, smoke and radiation detectors, lightemitting diodes and. A schematic representation of the cell, spray process and an iv curve is presented. The structural, optical and electrical properties of the resulting layers are discussed and related to the properties required in a highefficiency thinfilm solar cell. Furthermore, we used cadmium sulphide cds as an electron transport layer etl along with pcbm for the first time in inverted pscs.
Optical and structural properties of thermally evaporated cadmium sulphide thin films on silicon 1 0 0 wafers. Zinc cadmium sulphide and zinc sulphide as alternative heterojunction partners for cigs2 solar cells by bhaskar kumar b. However, given the possibility of polycrystalline thin films by vacuum evaporation, this semiconductor is very suitable to act as window material in many heterojunctions which invariably other material will act as absorber photons and have heterojunction cells. It was found that all the chosen pcs are capable of forming a hybrid heterojunction with the cds surface, and that. Lewis research center summary the effect of moisture on the stability of thinfilm cadmium sulfide cells was studied. Investigation of the properties of cadmium sulphide thin. Pdf cadmium sulfide nanostructures for photovoltaic devices. Pdf optical and structural properties of thermally. Cadmium sulfide cds is one of the most important iivi group semiconductors. Cadmium sulfide enhances solar cell efficiency sciencedirect. Recent improvements in efficiency and environmental stability ref.
Two different fabrication techniques were used for depositing the organic and inorganic layers of cupc and cds. Cadmium sulphide solar cells are photovoltaic devices in which heterojunctions are formed between ntype substrates of cadmium sulphide and ptype topotaxial layers of copper sulphide shiozawa et al 1969, stanley 1975. The observed changes in the photovoltaic output and spectral response were indicative of. The methods that have been used successfully for the production of cadmiumsulphide layers in thinfilm solar cells are described. However, the particle size and properties of the cdsn products depend largely on the synthesis methodologies. The cells produced consisted of a heterojunction between a merocyanine dye and cadmium sulphide. Pedotpss is used to increase the efficiency of the perovskite solar cell at ambient conditions. Ramasamy ssn research centre, ssn college of engineering, kalavakam603 110, chennai, tamilnadu, india corres. Denis ar con ljubljana, may 2011 abstract this seminar is a short overview of current photovoltaics.
Performance of graphenecds hybrid nanocomposite thin. Growth and characterization of high efficiency cdtecds solar cells. Synthesis and characterization of cadmium sulfide cds. Effect of moisture on cadmium sulfide solar cells by adolph e. Preparation and characterization of sn02, cds and pcds. Cadmium sulphide incorporated reduced graphene oxide as counter electrode material was synthesized from graphite using modified hummers method. The original laboratory spray process is briefly described and typical results are given for cells made this way. Sulphurization of the electrochemically deposited indium. Cadmium sulphidecadmium selenide quantum dot solar cells. Cadmium sulfide nanoparticles synthesized by microwave. Fabrication and characterization of spray pyrolysed. Fabrication and characterization of cadmium sulfide cds buffer layer.
Solar cells cadmium sulfide solar cells cadmium sulfide. D research scholar, advanced materials research lab, department of chemistry, loyola college, chennai, tamil nadu, india1. Pdf cadmium sulfide nanoparticles cdsn are excellent electron acceptor for hybrid solar cell applications. Characterization of cadmium zinc telluride solar cells. Request pdf highperformance cadmium sulphidebased planar perovskite solar cell and the cadmium sulphideperovskite interfaces planar heterojunction perovskite solar cell is one of the most. Investigation of the properties of cadmium sulphide thin films for solar cell. In this work, cdsn were synthetized by microwave heating using thioacetamide ta or thiourea tu as sulfur sources. Polymerfullerene blend solar cells with cadmium sulfide thin. Cadmium sulfide cds is an excellent photosensitive material and has a direct bandgap. Performance of np silicon and cadmium sulfide solar cells. Cu thin films preamble main objective of the present work is to develop a simple, low cost thin film solar cell using a very familiar semi conducting material like cadmium sulphide. In this study, buffer layer parameters layer thickness and buffer layer bandgap have been investigated by solar cell capacitance simulator scaps to find out the higher conversion efficiency.
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